amide reaction with alcohol

endobj x�S�*�*T0T0 B�����i�����U��� n)S�T ��� Summary. E-mail: �% Furthermore, both linear and b-branched aliphatic alcohols reacted smoothly to offer amides 6ab–ag in 91–95% isolated yields. the whole article in a third party publication with the exception of reproduction <>stream endstream Alcohols can also be converted to alkyl chlorides using thionyl chloride, SOCl 2, or phosphorous trichloride, PCl 3.; Alkyl bromides can be prepared in a similar reaction using PBr 3.; Used mostly for 1 o and 2 o ROH (via S N 2 mechanism); In each case a base is used to "mop-up" the acidic by-product. 20 0 obj Please enable JavaScript endobj Reactions of 2- and 3-thienyl alcohols with acetanilide, how-ever, needed to be conducted at 100 1C with 5 mol% of Ni(OAc) 2, which produced amides 6z and 6aa in 83% and 81% yields, respectively. x�+� � | ͐,.�. <>>>/BBox[0 0 625.44 818.36]/Length 122>>stream ��w3T�PI�2T0 BCcC#=s#c��\. ��w3T�PI�2T0 BCcC#=s#C#��\. do not need to formally request permission to reproduce material contained in this 16 0 obj x�s endobj 34 0 obj endstream it in a third party non-RSC publication you must The hydrogen bromide produced in the reaction combines with some of the excess ammonia, giving ammonium bromide as a by-product. 7 0 obj o����a����;!-��g��mJ�4�4E���:�0d�s�[_��;�'7��MD��;���e ��Fd�p��=�O��vu���e�|� ;��ן��K}!̿߯._�����x�ȁk}�����VxLy�i����&�y��nDHm�vY�P�԰���(�[��d��V����t�ȦWji+�e�Y�I��j%�C4�����_�oB�.��W�z���'��s]��s����w�����:�a �,�I]�Vg�>��!`��ۃ��T�a���(���Ez���p��QKgp�q��/�ɍ��]S��Yͪ����–���F�-��7��5���5�l\���f��8��Y�"�2�D�>C�R�&1�1�sQ5���th+��p̟7��"�������]u"E�Wf~D'�����r�����6h&�ª�I�_o6��6�>m��X��b�ɱ��*gԦ�S�M����� �|'ǝE��?�qb!�v���f���N)a�K�������zu�����H?t(o�Y_o.����*XY��3�9^�?ɎB�)o~]ov�� 1B�tC����D��� ��+���^nvTe�k~�%NK*I7� ���x����n-;���8�AB��q��]����&[e�"JPh�@��m"ߎ�Y���={����D�9A�H�� �, Michal Szostak, Malcolm Spain, Andrew J. Eberhart, and David J. Procter. endstream Carboxylic acid can be converted to amides by using DCC as an activating agent. �r� Reduction of Amides. of the whole article in a thesis or dissertation. endstream <>stream Authors contributing to RSC publications (journal articles, books or book chapters) endobj endobj The π electrons of the carboxyl group, , migrate to pick up the positive charge. <> Soc. Sun, L. Zhang, J. Yue, K. Fu, J. S. Zhou and B. Tang, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan, P. R. China, State Key Laboratory of Chemical Oncogenomics, Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Room F312, 2199 Lishui Road, Nanshan District, Shenzhen 518055, China, Instructions for using Copyright Clearance Center page.

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