Natl. TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director Tongberg, C.O. Aliphatic hydrocarbons, Acad. ; Soffer, M.B. Paul, Hanns-Ingolf; Krug, Joseph; Knapp, Helmut, Another route to 1-octene that has been used commercially on a small scale is dehydration of alcohols. Ziegler, K.; Dersch, F.; Wollthan, H., J. Chem. 1 0. peter n. 1 decade ago. and chemical property data is available from the Fluid Phase Equilibria, 2003, 210, 2, 277-285, https://doi.org/10.1016/S0378-3812(03)00174-2 Octane: Properties of the saturated liquid and vapor. The only commercial process to isolate 1-octene from a wide mixture of C8 hydrocarbons is practiced by Sasol, a South African oil and gas and petrochemical company. Chim. Soc., 1930, 52, 1032-1041. In industry, 1-octene is commonly manufactured by two main routes: oligomerization of ethylene and by Fischer–Tropsch synthesis followed by purification. Petrov, A.A.; Sergienko, S.R. NIST subscription sites provide data under the Recl. [all data], Desty and Whyman, 1957 Measurements of VLE, hE and vE for binary mixtures of n-alkanes with n-alkylbenzenes, ; Vasil'eva, I.I., Chim. ; Eisen, O.G., Bull. errors or omissions in the Database. J. 2. Solubilities of Liquid Stannic Iodide in several liquid Paraffins, ; Whitmore, F.C., Isomerization of Saturated Hydrocarbons Communication 1. Chem., Anal. Chem. 3. ; Liberman, A.L. Sci. Follow the links above to find out more about the data [all data], Kuus, Kudryavtseva, et al., 1980 Some fuels and their boiling points at atmospheric pressure: Volume III, Prop. ; Fenske, M.R., Acta, 41(7), 1958, 1915-1932. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:17590, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, 257-259 F / 760 mmHg (125-126.1111 °C / 760 mmHg), 258 F / 760 mmHg (125.5556 °C / 760 mmHg), Soluble in ether, Slightly soluble in alcohol. Pressure-volume-temperature relations in liquids and liquid mixtures. Standard Reference Data Act. Vapour-liquid equilibria. ; Overhoff, J.; Smittenberg, J.; Benninga, N.; Bouman, G.P. NIST Standard Reference J. Appl. Ewing, M.B. ; Taylor, W.J. The boiling point is defined as the temperature at which the saturated vapor pressure of a liquid is equal to the surrounding atmospheric pressure. Data, 1968, 13, 301-4. Chem. Thermodynamic Studies of n-Alkane-n-Alkyne Systems 2. and Informatics, NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data), NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). The boiling point is defined as the temperature at which the saturated vapor pressure of a liquid is equal to the surrounding atmospheric pressure. Forziati, A.F. following TRC products: Ambrose and Tsonopoulos, 1995 Ann. [all data], Treszczanowicz and Treszczanowicz, 1979 J. Chim. Temperature (K) A B C Reference Comment; 216.59 - 297.10: 5.2012: 1936.281-20.143: Carruth and Kobayashi, 1973: Coefficents calculated by NIST from author's data. of Hydrocarbons of Low Mol. Izv. Octane is flammable and moderately toxic. Rep., Ohio State Univ., Aug. 31, 1940. the VI. [all data], Zieborak and Wyrzykowska-Stankiewicz, 1958 Isothermal Vapor-Liquid Equilibria in Binary Mixtures Contining Alkanes and Ethers, (kJ/mol) C. R. Hebd. Pet. Sci. Chem., 1970, 44, 1255. Natl. . Z. Phys. J. [all data], Brame and Hunter, 1927 Anonymous, R., It is used for the Octane Number calibration of antiknock properties of fuels. The Critical Temperatures of Mixtures formed by Benzene and n-Octane with Iso-Alcohols, Octane is a hydrocarbon and an alkane with the chemical formula C8H18, and the condensed structural formula CH3(CH2)6CH3. [all data], Anonymous, 1940 3 (CH. Wibaut, J.P.; Hoog, H.; Lagedijk, S.L. Soc., 1954, 76, 6364. Prior to the 1970s, 1-octene was also manufactured by thermal cracking of waxes, whereas linear internal octenes were also manufactured by chlorination/dehydrochlorination of linear alkanes. InChI=1S/C8H18/c1-3-5-7-8-6-4-2/h3-8H2,1-2H3 Chem. [all data], Hoffmann, Ess, et al., 1956 ; Gross, M.E. Pays-Bas, 1939, 58, 329. Boord, C.E. ; Wiegand, R.V. Soc. In recent years, two on-purpose 1-octene technologies have been commercialised: a butadiene telomerization plant (Dow, Tarragona), and a 1-heptene to 1-octene plant based on a Fischer-Tropsch-derived C7 olefin stream (Sasol, Secunda). Natl. on behalf of the United States of America. Thermochimica Acta, 1986, 108, 9-27, https://doi.org/10.1016/0040-6031(86)85073-0 Data compiled as indicated in comments: In typical circumstances, 1-hexene content of the entire distribution of alpha-olefins ranges from about 25% of the distribution in the Ethyl (Innovene) process to about 8% of distribution in some modes of the Gulf (CP Chemicals) and Idemitsu processes. [all data], Prabhu and Van Winkle, 1964 ; Rao, M.V.P., . Alkali Organic Compounds XI. [all data], Boord, Greenlee, et al., 1946 [all data], Huffman, Parks, et al., 1931 ; Tsedlina, A.L. The Wolf-Kishner Reaction at Atmospheric Pressure, However, NIST makes no warranties to that effect, and NIST ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein Michou-Saucet, Marie-Annie; Jose, Jacques; Michou-Saucet, Christian; Merlin, J.C., Czech. Tassios, D.; Van Winkle, M., [all data], Galska-Krajewska, 1970 Khim. ; Speyers, C.L. [all data], Finke, Gross, et al., 1954 Its principle use is as a component of gasoline, and the performance of this gasoline depends on its octane rating which gets its name from this molecule. Uncertainty assigned by TRC = 0.2 K; from Int. As is the case with other hydrocarbons, octane undergoes hydrocarbon combustion, combining with oxygen to form carbon dioxide. Soc., 1932, 54, 3706-10. Data, 1995, 40, 531-546. errors or omissions in the Database. [all data], Zieborak, Kaczorowna-Badyoczek, et al., 1955 Ind. Weight, Am. Beaton, C. F. and Hewitt G. F. (1989) Physical Property Data for the Design Engineer, Hemisphere Publishing Corporation, New York. ; Hansen, R.D., The purpose of the fee is to recover costs associated Rep., Ohio State Univ., Aug. 31, 1939. J. Res. Vapor-Liquid Equilibria at Subatmospheric Pressures of the Ethylcyclohexane-n-Octane System, TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director J. [all data], Brewster, 1954 ; Whitmore, F.C. ; Piotrovskaya, E.M., Vapor-Liquid Equilibria of Ethanol + Octane at 343.15 K and 1-Propanol + Octane at 358.15 K, Ber., 1910, 43, 397. Justus Liebigs Ann. Monatsh. 4 Spectral Information Expand this section. Chem. Thermal data on organic compounds. Prabhu, P.S. Temperature dependence of heats of vaporization of saturated hydrocarbons C5-C8; Experimental data and an estimation method, [all data], Bondi, 1963 J. Chem. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Soc., 1931, 53, 1948. Inst. and Phys. 2020-11-15. Thermal data on organic compounds. [all data], Landolt and Jahn, 1892 X. Akad. J. Chem. Soc., 1955, 1955, 4076. 1-Octene is an organic compound with a formula CH2CHC6H13. Khim. Chem. Everything else being the same, ie the same class of compouns , in this case alkanes, The heavier molecular weight compound will have a higher boiling point. Natl. Foehr, E.G. ; Kazanskii, B.A., Series of Binary Azeotropes Formed by Aniline, o-Toluidine and m-Xylidine with Normal Paraffinic Hydrocarbons, ; Lu, B.C.Y., Stand. Natl. Your institution may already be a subscriber.
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